Characterization of fresh and weathered petroleum for potential impacts to soil fertility

In many petroleum-producing regions, there are not adequate controls to prevent pipeline breaks and spills, and thus soil is frequently contaminated with petroleum hydrocarbons. Different petroleum oil compounds may produce negative impacts on soil fertility. In this study, four fresh crudes, a weathered petroleum, and oils from bioremediated and burned sites were investigated (specific gravities 0.83–1.27). Fourier transform infrared spectroscopy revealed three predominant polar functional groups to be more plentiful in the heavier crudes. The relative abundance of these groups was used to calculate an index that was directly correlated with specific gravity (R ² = 0.9960) and the percent of asphaltene plus (polars + resins) fractions in the oil (R ² = 0.9643). This index correlated exponentially to the water repellency caused by petroleum in an alluvial soil (R ² = 0.9928). Furthermore, extra-heavy oil at a concentration of 10,000 ppm, the maximum allowable oil concentration in the soil that is within regulatory norms in many US states and other countries, and with a specific gravity >1.002, showed severe water repellency. This study presents an alternative for determining soil remediation criteria based on the API gravity of the oil rather than the C-range of the hydrocarbon mixtures, simplifying analytical methods and systematically studying the interaction between the kinds of petroleum mixtures and potential impacts to soil fertility.     

Long- and short-term volcanic hazard assessment of El Chichón Volcano (Mexico) through Bayesian inference

Natural Hazards - The 1982 eruption of El Chichón volcano constitutes the worst volcanic disaster in Mexico producing more than 2000 fatalities, thousands of displaced people and severe...     

Palaeoceanographic changes in the North Atlantic during the Mid‐Pleistocene Transition (MIS 31–19) as inferred from planktonic foraminiferal and calcium carbonate records

Marine sediments from the Integrated Ocean Drilling Project (IODP) Site U1314 (56.36°N, 27.88°W), in the subpolar North Atlantic, were studied for their planktonic foraminifera, calcium carbonate content, and Neogloboqudrina pachyderma sinistral (sin.) δ¹³C records in order to reconstruct surface and intermediate conditions in this region during the Mid‐Pleistocene Transition (MPT). Variations in the palaeoceanography and regional dynamics of the Arctic Front were estimated by comparing CaCO₃ content, planktonic foraminiferal species abundances, carbon isotopes and ice‐rafted debris (IRD) data from Site U1314 with published data from other North Atlantic sites. Site U1314 exhibited high abundances of the polar planktonic foraminifera N. pachyderma sin. and low CaCO₃ content until Marine Isotope Stage (MIS) 26, indicating a relatively southeastward position of the Arctic Front (AF) and penetration of colder and low‐salinity surface arctic water‐masses. Changing conditions after MIS 25, with oscillations in the position of the AF, caused an increase in the northward export of the warmer North Atlantic Current (NAC), indicated by greater abundances of non‐polar planktonic foraminifera and higher CaCO₃. The N. pachyderma sin. δ¹³C data indicate good ventilation of the upper part of the intermediate water layer in the eastern North Atlantic during both glacial and interglacial stages, except during Terminations 24/23, 22/21 and 20/1. In addition, for N. pachyderma (sin.) we distinguished two morphotypes: non‐encrusted and heavily encrusted test. Results indicate that increases in the encrusted morphotype and lower planktonic foraminiferal diversity are related to the intensification of glacial conditions (lower sea‐surface temperatures, sea‐ice formation) during MIS 22 and 20.     

Energy balance and evaporation loss of an agricultural reservoir in a semi‐arid climate (south‐eastern Spain)

A typical agricultural water reservoir (AWR) of 2400 m² area and 5 m depth, located in a semi‐arid area (southern Spain), was surveyed on a daily basis for 1 year. The annual evaporation flux was 102·7 W m^?2, equivalent to an evaporated water depth of 1310 mm year^?1. The heat storage rate G exhibited a clear annual cycle with a peak gain in April (G ～ 45 W m^?2) and a peak loss in November (G ～ 40 W m^?2), leading to a marked annual hysteretic trend when evaporation (λE) was related to net radiation (R_n). λE was strongly correlated with the available energy A, representing 91% of the annual AWR energy loss. The sensible heat flux H accounted for the remaining 9%, leading to an annual Bowen ratio in the order of 0·10. The equilibrium and advective evaporation terms of the Penman formula represented 76 and 24%, respectively, of the total evaporation, corresponding to a annual value of the Priestley–Taylor (P–T) coefficient (α) of 1·32. The P–T coefficient presented a clear seasonal pattern, with a minimum of 1·23 (July) and a maximum of 1·65 (December), indicating that, during periods of limited available energy, AWR evaporation increased above the potential evaporation as a result of the advection process. Overall, the results stressed that accurate prediction of monthly evaporation by means of the P–T formula requires accounting for both the annual cycle of storage and the advective component. Some alternative approaches to estimating R_n, G and α are proposed and discussed. Copyright © 2009 John Wiley & Sons, Ltd.     

Calculated and observed seismic behaviour of exposed upper mantle

In order to determine the seismic properties of rocks representing the continental crust/upper mantle transition, a structural and petrographical study of peridotites of the Ivrea-Verbano zone (N. Italy) has been undertaken. The seismic behaviour (Vp, Vs, birefringence, orientation of the fast shear-wave polarisation plane) has been calculated from the modal composition of rock samples, together with the crystallographic preferred orientation and the single crystal elastic constants, using the methods of Mainprice (1990). It is shown that the intrinsic anisotropy of peridotites is mainly due to the lattice preferred orientation (LPO) of olivine and to the competing effects due to the LPO of orthopyroxene. If present, well-oriented hydrous phases such as phlogopite, leads to both P- and S-waves velocities becoming drastically reduced, but the anisotropy and the S-wave splitting (mainly on the foliation plane) is increased. An attempt has been made to apply this petrologic and microstructural approach to understand the seismic properties of ultramafic rocks with the aid of a mobile seismic network set up in the Ivrea-Verbano zone. Five recording units with 3-component geophones were installed on the most representative lithologies of the Ivrea-Verbano zone: kinzigites, gabbros, stronalites, and on metapelites of the adjacent outcrop of the Serie dei Laghi. During five months the seismic network recorded 49 events that were mainly regional earthquakes. The preliminary analysis of the first arrival revealed a high-velocity anomaly near the Finero ultramafic massif. Rough calculations indicated that this anomaly could be due to a shallow-depth, peridotitic body about six kilometres thick. S-wave polarisation analysis was carried out on the horizontal components of the seismograms of four regional earthquakes that showed a first arrival propagating almost vertically at the recording sites. Four earthquakes were chosen in order to reconstruct the orientation of the polarisation plane of the shear phases. The preliminary results of this analysis have shown a qualitatively good agreement between the orientation of the polarisation plane of the fast shear-wave and the strike of the foliation at the station near Finero, located on kinzigites of the Ivrea-Verbano zone, although the relationships between the local structural setting and the polarisation orientations at the other recording sites is not yet so clear.     

The 2001 Mesoscale Convective Systems over Iberia and the Balearic Islands

Summary This paper characterizes Mesoscale Convective Systems (MCSs) during 2001 over Iberia and the Balearic Islands and their meteorological settings. Enhanced infrared Meteosat imagery has been used to detect their occurrence over the Western Mediterranean region between June and December 2001 according to satellite-defined criteria based on the MCS physical characteristics. Twelve MCSs have been identified. The results show that the occurrence of 2001 MCSs is limited to the August–October period, with September being the most active period. They tend to develop during the late afternoon or early night, with preferred eastern Iberian coast locations and eastward migrations. A cloud shield area of 50.000 km² is rarely exceeded. When our results are compared with previous studies, it is possible to assert that though 2001 MCS activity was moderate, the convective season was substantially less prolonged than usual, with shorter MCS life cycles and higher average speeds. The average MCS precipitation rate was 3.3 mm·h⁻¹ but a wide range of values varying from scarce precipitation to intense events of 130 mm·24 h⁻¹ (6 September) were collected. The results suggest that, during 2001, MCS rainfall was the principal source of precipitation in the Mediterranean region during the convective season, but its impact varied according to the location. Synoptic analysis based on NCEP/NCAR reanalysis show that several common precursors could be identified over the Western Mediterranean Sea when the 2001 MCSs occurred: a low-level tongue of moist air and precipitable water (PW) exceeding 25 mm through the southern portion of the Western Mediterranean area, low-level zonal warm advection over 2 °C·24 h⁻¹ towards eastern Iberia, a modest 1000–850 hPa equivalent potential temperature (θ_e) difference over 20 °C located close to the eastern Iberian coast, a mid level trough (sometimes a cut-off low) over Northern Africa or Southern Spain and high levels geostrophic vorticity advection exceeding 12·10⁻¹⁰ s⁻² over eastern Iberia and Northern Africa. Finally, the results suggest that synoptic, orographic and a warm-air advection were the most relevant forcing mechanisms during 2001.     

Modeling of dioctahedral 2:1 phyllosilicates by means of transferable empirical potentials

 Dioctahedral 2:1 phyllosilicates with different interlayer charge have been studied theoretically by using transferable empirical interatomic potentials. The crystal structures of pyrophyllite, muscovite, margarite, beidellite, montmorillonite, and different smectites and illites have been simulated. The interatomic potentials were able to reproduce the experimental structure of phyllosilicates with high, medium and low interlayer charge. The calculated structures are in agreement with experiment for the main structural features of the crystal lattice. The effect of the cation substitution in the octahedral and tetrahedral sheets on the structural features has been also studied. Good linear relationships have been found, and the calculated effects are consistent with experimental results. Some unknown structural features of the crystal structures of clays are predicted in this work. Received: 8 March 2000 / Accepted: 19 September 2000     

Finding regions of influence on SO2 and SO= 4 daily concentration measurements at four sites in Spain

Contamination by the pollutants SO₂ and SO⁼₄ was analyzed for the 1989–1992 period at four regional stations in Spain under the auspices of the EMEP-BAPMON program. The evolution of the time series of the daily pollution has also been assessed, and high mean concentrations at La Cartuja and Logroño observed, with values of 3.8 and 4.5 g m⁻³ for SO₂, respectively. Maximum annual concentrations were recorded in 1989, when SO₂ reached values of 6.24, 5.39, 5.71, and 9.30 g m⁻³ for the stations of La Cartuja, San Pablo de los Montes, Roquetas, and Logroño, respectively. This work attempts to establish a relationship between the concentrations of the pollutants - both SO₂ gas and SO⁼₄ aerosol - and the zones of emission or persistence of these long-range transported pollutants. In this way, those regions showing a greater impact on the air quality in each season have been determined. To achieve this, the trajectories of the air masses carrying away the pollution to each of the receiving stations were considered and followed by a sectorial analysis. Nonparametric statistical methods were implemented to contrast the chemical homogeneity among the different sectors. The criterion that several homogeneous sectors form a chemically homogeneous region was used. To improve this sectorial analysis, we have proposed a new technique based on the Potential-Source-Contribution Function (PSCF). Starting out from a set of specified regions, considered to be chemically homogeneous domains, it is possible to determine the likelihood that an air mass with particular characteristics (e.g., that a value of the daily concentration higher than the mean recorded at the station has been obtained) will arrive at a given station after having crossed one of the previously defined regions. Using this technique, it is possible to determine the source regions through which the air masses circulate and bring high pollution concentrations to the studied stations. Thanks to the PSCF, these statistical methods offer, through a sectorial analysis, the possibility to pass from a qualitative to a more quantitative view.     

Peralkaline acid tendencies in Gran Canaria (Canary Islands)

The study of a volcanic series from the island of Gran Canaria (Canary Islands) in which alkaline and peralkaline, saturated and undersaturated rocks coexist, is reported here. Materials with high volatile content (ignimbritic trachytes) were first emitted and the series ended with the eruption of phonolitic lavas. The average peralkalinity index in these rocks is typically about 1.0 and, therefore, peralkaline rocks coexist with non-peralkaline ones. However, a maximum in peralkalinity is found in the ignimbritic rocks of the lower part of the series. In spite of the evident acid peralkaline tendencies of these rocks, it does not seem appropriate to classify them as pantellerites or comendites. Nor are they consistent with the genetic processes proposed for rocks of similar composition and oceanic environment.The crystallization of the feldspars controls the variation trends among the different magmas but the fractionation alone does not sufficiently explain the genesis of successive fluids. Various factors seem to point to the important role which a gas-transfer process causing a geochemical stratification inside the magmatic chamber may have played.The occurrence of peralkaline silicics at Gran Canaria, which is located for away from the active Mid-Atlantic ridge, is not related to transitional basalts. These rocks are a deviation from the main undersaturated alkalic trend which characterizes the volcanism of the Canary Islands, their genesis being related to the realization of favourable local volcanic conditions.     

Solar rotation in the subphotospheric layers

The solar rotation rate at latitudes 0°, 15° and 30° has been inferred by averaging the results of 120 regions of 15°×15°, which have been studied over a total area of about 75° in latitude and 360° in longitude. A local helioseismology technique, the ring diagram analysis method, has been used to analyse the horizontal velocity vectors from about 0.95 R up to the surface. Our results are in very good agreement with those of other authors over most of the depth range. However, near the surface we find sharp local features which are not reported in other studies. The independent measurements of the rotation rate in the north and south hemispheres show asymmetries below 0.975 R . The data used are full-disc dopplergrams taken by Solar Oscillation Investigation/Michelson Doppler Imager (SOI/MDI) on board of the SOlar and Heliospheric Observatory (SOHO) during its first Dynamic Program, between 1996 May and June.